Title of article
Crystal structure of bis(bis{μ3-3-methyl-3-[(4-nitro-2-oxidobenzylidene)amino]propane-1,3-diolato}tris[chlorido(dimethyl sulfoxide)iron(III)]) dimethyl sulfoxide heptasolvate dihydrate
Author/Authors
Chygorin, Eduard Department of Inorganic Chemistry - Taras Shevchenko National University of Kyiv, Ukraine , Smal, Yuri Department of Inorganic Chemistry - Taras Shevchenko National University of Kyiv, Ukraine , Omelchenko, Irina V. SSI `Institute for Single Crystals' NAS of Ukraine, Ukraine
Pages
17
From page
1
To page
17
Abstract
The title compound, [Fe3(C11H11N2O5)2Cl3(C2H6OS)3]2·7C2H6OS·2H2O, was isolated accidentally from an Fe0–NiCl2·6H2O–H3L–TEA–DMSO system [where H3L is the product of the condensation between p-nitrosalicylaldehyde and 2-amino-2-methylpropane-1,3-diol and dimethyl sulfoxide (DMSO), and TEA is triethylamine]. The structure is based on a trinuclear {Fe3(μ-O)4} core, with an angular arrangement of the FeIII ions that can be explained by the geometrical restrictions of two bulky ligands, each coordinating to all of the metal cations.
Keywords
crystal structure , Schiff base ligand , iron(III) , trinuclear
Journal title
Acta Crystallographica Section E: Crystallographic Communications
Serial Year
2016
Record number
2620439
Link To Document