Title of article :
Crystal structure of chlorido[1-(4-nitrophenyl)thiourea-κS]bis(triphenylphosphane-κP)copper(I)
Author/Authors :
Nimthong-Roldá, Arunpatcha Department of Chemistry - Boston University, USA , Promsuwhan, Nichakan Department of Chemistry, Faculty of Science - Prince of Songkla University, Thailand , Puetpaiboon, Walailak Department of Chemistry- Faculty of Science - Prince of Songkla University,Thailand , Wattanakanjana, Yupa Department of Chemistry- Faculty of Science - Prince of Songkla University,Thailand
Abstract :
The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetrahedral coordination sphere around the CuI atom, with two P atoms from two triphenylphosphane molecules, one terminal S atom from a 1-(4-nitrophenyl)thiourea molecule and a chloride ion as ligands. An intramolecular N—H⋯Cl hydrogen bond stabilizes the molecular conformation [graph-set motif R22(6)]. In the crystal, further N—H⋯Cl hydrogen bonds connect individual molecules into zigzag chains parallel to [001]. The chains are linked by weak C—H⋯O hydrogen-bonding interactions into a three-dimensional network.
Keywords :
crystal structure , intra- and intermolecular hydrogen bonding , N—H⋯Cl hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
