Author/Authors :
Chiang, Hojae Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences - Gyeongsang National University, Republic of Korea , Kim,Tae Ho Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences - Gyeongsang National University, Republic of Korea , Park, Hyunjin Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences - Gyeongsang National University, Republic of Korea , Kim, Jineun Department of Chemistry (BK21 plus) and Research Institute of Natural Sciences - Gyeongsang National University, Republic of Korea
Abstract :
The reaction of copper(I) iodide with N-acetylthiomorpholine (L, C6H11NOS) in acetonitrile results in a coordination polymer with composition [CuI(L)2]n. The CuI atom is coordinated by two S atoms and two I atoms, adopting a distorted tetrahedral environment. The μ2-bridging mode of the I atoms gives rise to chains extending parallel to [010]. C—H⋯O hydrogen-bonding interactions between the chains lead to a three-dimensional network.
Keywords :
crystal structure , copper(I) iodide , coordination polymer , N-acetylthiomorpholine
