• Title of article

    Crystal structure of the solid solution Ba8.35Pb0.65(B3O6)6

  • Author/Authors

    Zhao. Wenwu Department of Environmental and Chemical Engineering - Tangshan College, People's Republic of China

  • Pages
    9
  • From page
    1
  • To page
    9
  • Abstract
    Single crystals of lead barium borate, Ba8.35Pb0.65(B3O6)6, octabarium lead(II) hexa­kis­(triborate), have been obtained by spontaneous nucleation from a high-temperature melt. Its three-dimensional structure is constructed on the basis of a BaO9 polyhedron, a (Pb/Ba)O6 octa­hedron (occupancy ratio Pb:Ba = 0.216:0.784) and a condensed B3O6 ring anion. In the crystal, the planar B3O6 anions are stacked in an alternating fashion with Ba and (Pb/Ba) atoms along [001]. A comparison is made with the structures of related solid solutions in the system Ba/Pb/B/O.
  • Keywords
    crystal structure , solid solution , spontaneous nucleation , borate
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Full Text URL
    journals.iucr.org/e/issues/2017/03/00/wm5348/wm5348.pdf
  • Record number

    2621332

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2621332