Title of article :
Crystal structure of β-benzyl DL-aspartate N-carboxyanhydride
Author/Authors :
Kanazawa, Hitoshi Faculty of Symbiotic Systems Science - Fukushima University, Japan , Inada, Aya Faculty of Symbiotic Systems Science - Fukushima University, Japan
Abstract :
In the title racemic compound, C12H11NO5 [systematic name: benzyl 2-(2,5-dioxooxazolidin-4-yl)acetate], the oxazolidine ring is planar, with an r.m.s. deviation of 0.03 Å. The benzyl ring is almost normal to the oxazolidine ring, making a dihedral angle of 80.11 (12)°. In the crystal, inversion dimers are formed between the L- and D-enantiomers via pairs of N—H⋯O hydrogen bonds. This arrangement is favourable for the polymerization of the compound in the solid state. The dimers are linked by C—H⋯O hydrogen bonds, forming layers parallel to the ab plane.
Keywords :
crystal structure , solid state polymerization , amino acid , N-carboxyanhydride , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications