Title of article :
A two-dimensional coordination polymer: poly[bis[μ2-N-ethyl-N-(pyridin-4-ylmethyl)dithiocarbamato-κ3N:S,S′]cadmium(II)] 3-methylpyridine monosolvate]
Author/Authors :
Arman, Hadi D. Department of Chemistry - The University of Texas at San Antonio, USA , Poplaukhin, Pavel Chemical Abstracts Service, USA , Tiekink, Edward R. T. Centre for Crystalline Materials - School of Science and Technology - Sunway University, Malaysia
Abstract :
The title compound, {[Cd(C9H11N2S2)2]·C6H7N}n, features two μ2-κ3-dithiocarbamate ligands each of which chelates one CdII atom, via the S atoms, while simultaneously bridging to another via the pyridyl-N atom. The result is a two-dimensional coordination polymer extending parallel to the ab plane with square channels along the b axis. The CdII atom geometry is based on a distorted cis-N2S4 octahedron. The 3-methylpyridine molecules reside in the channels aligned along the b axis, being held in place by methylene-C—H⋯N(3-methylpyridine) and (3-methylpyridine)-C—H⋯π(pyridyl) interactions. Pyridyl-C—H⋯S and dithiocarbamate-methyl-C—H⋯π(pyridyl) interactions provide connections between layers along the c axis.
Keywords :
crystal structure , hydroxypyridine , dithiocarbamate , cadmium , coordination polymer
Journal title :
Acta Crystallographica Section E: Crystallographic Communications