• Title of article

    Crystal structure of trans-di­chloridobis­[N-(5,5-di­methyl-4,5-di­hydro-3H-pyrrol-2-yl-κN)acetamide]palladium(II) dihydrate

  • Author/Authors

    Lasri, Jamal Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia , Eltayeb, Naser Eltaher Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia , Haukka, Matti University of Jyväskylä - Department of Chemistry - University of Jyväskylä, Finland , Babgi, Bandar A. Department of Chemistry - Rabigh College of Science and Arts, Saudi Arabia

  • Pages
    9
  • From page
    1
  • To page
    9
  • Abstract
    The title complex, [PdCl2(C8H14N2O)2]·2H2O, was obtained by N–O bond cleavage of the oxa­diazo­line rings of the trans-[di­chlorido-bis­(2,5,5-trimethyl-5,6,7,7a-tetra­hydro­pyrrolo­[1,2-b][1,2,4]oxa­diazole-N1)]palladium(II) complex. The palladium(II) atom exhibits an almost square-planar coordination provided by two trans-arranged chloride anions and a nitro­gen atom from each of the two neutral organic ligands. In the crystal, N—H⋯O, O—H⋯O and O—H⋯Cl hydrogen bonds link complex mol­ecules into double layers parallel to the bc plane.
  • Keywords
    crystal structure , N—O bond cleavage , cyclo­addition , nitrone , palladium
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Full Text URL
    journals.iucr.org/e/issues/2017/04/00/rz5207/rz5207.pdf
  • Record number

    2621543

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=2621543