Title of article :
Crystal structure of O-benzyl-L-tyrosine N-carboxy anhydride
Author/Authors :
Inada, Aya Faculty of Symbiotic Systems Science - Fukushima University, Japan , Kanazawa, Hitoshi Faculty of Symbiotic Systems Science - Fukushima University, Japan
Abstract :
In the title compound, C17H15NO4 (alternative name; O-benzyl-L-tyrosine N-carboxy anhydride), the oxazolidine ring is planer, with an r.m.s. deviation of 0.039 Å. The benzyloxy and benzyl rings are almost coplanar, making a dihedral angle of 0.078 (10)°, and are inclined to the oxazolidine ring by 59.16 (11) and 58.42 (11)°, respectively. In the crystal, molecules are linked by N—H⋯O and C—H⋯O hydrogen bonds, forming ribbons propagating along [010]. The ribbons are linked by C—H⋯π interactions, forming a three-dimensional supramolecular structure. The oxazolidine rings of adjacent ribbons are arranged into a layer parallel to the ab plane. This arrangement is favourable for the polymerization of the compound in the solid state.
Keywords :
crystal structure , L-tyrosine , L-amino acid N-carboxy anhydride , C—H⋯π interactions , hydrogen bonding , solid-state polymerization , O-benzyl-L-tyrosine NCA
Journal title :
Acta Crystallographica Section E: Crystallographic Communications