Author/Authors :
Rivera, Augusto Universidad Nacional de Colombia, Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Miranda-Carvaja,Ingrid Universidad Nacional de Colombia, Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Ríos-Motta, Jaime Universidad Nacional de Colombia, Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Bolte, Michael Institut für Anorganische Chemie - J. W. Goethe-Universität Frankfurt, Germany
Abstract :
In the title compound, C17H18N2O, the central carbon atom with the OH substituent and one of the (E)-benzylideneamino substituents are disordered over two sets of sites with occupancies of 0.851 (4) and 0.149 (4). The relative positions of the two disorder components is equivalent to a rotation of approximately 60° about the C—N single bond. In the crystal, the molecules are held together by O—H⋯N hydrogen bonds, forming simple C(5) chains along the b-axis direction. In addition, pairs of the chains are further aggregated by weak C—H⋯π interactions.
Keywords :
crystal structure , hydrogen bonding , C—H⋯π interactions , Schiff bases