Title of article :
1,3-Bis{(E)-[4-(di­methyl­amino)­benzyl­­idene]amino}­propan-2-ol: chain structure formation via an O—H⋯N hydrogen bond
Author/Authors :
Rivera, Augusto Universidad Nacional de Colombia- Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Miranda-Carvajal, Ingrid Universidad Nacional de Colombia- Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Ríos-Motta, Jaime Universidad Nacional de Colombia- Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Bolte, Michael Institut für Anorganische Chemie - J. W. Goethe-Universität Frankfurt ,Germany
Pages :
9
From page :
1
To page :
9
Abstract :
The asymmetric unit of the title compound, C21H28N4O, consists of two unique mol­ecules linked by an O—H⋯N hydrogen bond. The conformation of both C=N bonds is E and the azomethine functional groups lie close to the plane of their associated benzene rings in each of the independent mol­ecules. The dihedral angles between the two benzene rings are 83.14 (4) and 75.45 (4)°. The plane of the one of the N(CH3)2 units is twisted away from the benzene ring by 18.8 (2)°, indicating loss of conjugation between the lone electron pair and the benzene ring. In the crystal structure, O—H⋯N hydrogen bonds together with C—H⋯O hydrogen bonds link neighbouring supra­molecular dimers into a three-dimensional network.
Keywords :
crystal structure , Schiff bases , supra­molecular chain , super-structure , pseudo-symmetry
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2017
Full Text URL :
Record number :
2621825
Link To Document :
بازگشت