• Title of article

    Crystal structure of 2,2′-(ethane-1,2-di­yl)bis­­(2,3-di­hydro-1H-naphtho­[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines

  • Author/Authors

    Rivera. Augusto Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Cepeda-Santamaríaa, Juan E. Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Ríos-Motta, Jaime Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Bolte, Michael Institut für Anorganische Chemie - J. W. Goethe-Universität Frankfurt, Max-von Laue-Strasse 7, 60438 Frankfurt/Main, Germany

  • Pages
    7
  • From page
    1
  • To page
    7
  • Abstract
    In the title compound, C26H24N2O2, the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the mol­ecule, which lies about an inversion centre. The C atoms of the ethyl­ene spacer group adopt an anti­periplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supra­molecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component.
  • Keywords
    crystal structure , short contacts , benzoxazines , phenolic resins
  • Journal title
    Acta Crystallographica Section E: Crystallographic Communications
  • Serial Year
    2017
  • Record number

    2621844