Title of article :
Crystal structure of 2,2′-(ethane-1,2-diyl)bis(2,3-dihydro-1H-naphtho[1,2-e][1,3]oxazine): a prospective raw material for polybenzoxazines
Author/Authors :
Rivera. Augusto Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Cepeda-Santamaríaa, Juan E. Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Ríos-Motta, Jaime Universidad Nacional de Colombia - Sede Bogotá - Facultad de Ciencias - Departamento de Química, Colombia , Bolte, Michael Institut für Anorganische Chemie - J. W. Goethe-Universität Frankfurt, Max-von Laue-Strasse 7, 60438 Frankfurt/Main, Germany
Abstract :
In the title compound, C26H24N2O2, the oxazine moiety is fused to a naphthalene ring system. The asymmetric unit consists of one half of the molecule, which lies about an inversion centre. The C atoms of the ethylene spacer group adopt an antiperiplanar arrangement. The oxazine ring adopts a half-chair conformation. In the crystal, supramolecular chains running along the b axis are formed via short C—H⋯π contacts. The crystal studied was a non-merohedral twin with a fractional contribution of 0.168 (2) of the minor twin component.
Keywords :
crystal structure , short contacts , benzoxazines , phenolic resins
Journal title :
Acta Crystallographica Section E: Crystallographic Communications