Author/Authors :
Naghiyev, Farid N. Department of Chemistry - Baku State University, Azerbaijan , Khrustalev, Victor N. Peoples' Friendship University of Russia (RUDN University), Russian Federation , Akkurt, Mehmet Department of Physics - Faculty of Sciences - Erciyes University, Turkey , Huseynov, Elnur Z. Department of Chemistry - Baku State University, Azerbaijan , Khalilov, Ali N. Department of Chemistry - Baku State University, Azerbaijan , Akobirshoev, Anzurat A. Acad Sci Republ Tadzhikistan - Kh Yu Yusufbekov Pamir Biol Inst, Tajikistan , Akobirshoev, Anzurat A. Department of Chemistry - Baku State University, Azerbaijan
Abstract :
In the title compound, C25H22N2O3S·0.04H2O, the central cyclohexane ring adopts a chair conformation. In the crystal, molecules are linked by N—H⋯O, C—H⋯O, and C—H⋯N hydrogen bonds, forming the molecular layers parallel to the bc plane, which interact by the van der Waals forces between them. A Hirshfeld surface analysis indicates that the contributions from the most prevalent interactions are H⋯H (41.2%), C⋯H/H⋯C (20.3%), O⋯H/H⋯O (17.8%) and N⋯H/H⋯N (10.6%).
Keywords :
crystal structure , 1,2,7,8-tetrahydroisoquinoline ring system , Hirshfeld surface analysis
