Title of article :
Crystallographic and spectroscopic characterization of 3-chloro-5-fluorosalicylaldehyde
Author/Authors :
Triggs, Christopher T. Department of Chemistry - Vassar College, USA , Tanski, Joseph M. Department of Chemistry - Vassar College, USA
Abstract :
The title compound (systematic name: 3-chloro-5-fluoro-2-hydroxybenzaldehyde), C7H4ClFO2, is a dihalogenated salicylaldehyde derivative that has been studied for its antibacterial characteristics. The salicylaldehyde engages in intramolecular hydrogen bonding with an O—H⋯O distance of 2.6231 (19) Å while the molecules pack together via weak intermolecular C—H⋯O, C—H⋯F and F⋯O interactions and offset face-to-face π-stacking.
Keywords :
crystal structure , hydrogen bonding , halogenated salicylaldehyde derivative , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications