Title of article :
Crystal structure and Hirshfeld analysis of di-tert-butyl 2,2′-[(ethyl­aza­nedi­yl)bis­­(methyl­ene)]bis­­(1H-pyrrole-1-carboxyl­ate)
Author/Authors :
Kvyatkovskay, Elizaveta A. Faculty of Science - Peoples' Friendship University of Russia (RUDN University), Russian Federation , Atioğlu, Zeliha İlke Education and Health Foundation - Cappadocia University - Cappadocia Vocational College - The Medical Imaging Techniques Program, Turkey , Akkurt, Mehmet Department of Physics - Faculty of Sciences - Erciyes University, Turkey , Epifanova, Polina P. Faculty of Science - Peoples' Friendship University of Russia (RUDN University), Russian Federation , Valchuk, Karina S. Faculty of Science - Peoples' Friendship University of Russia (RUDN University), Russian Federation , Khrustalev, Victor N. Faculty of Science - Peoples' Friendship University of Russia (RUDN University), Russian Federation , Bhattarai, Ajaya Department of Chemistry - M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal
Pages :
11
From page :
1
To page :
11
Abstract :
a Faculty of Science, Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation, b ¤lke Education and Health Foundation, Cappadocia University, Cappadocia Vocational College, The Medical Imaging Techniques Program, 50420 Mustafapas¸a, U¨ rgu¨p, Nevs¸ehir, Turkey, c Department of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, Turkey, d N. D. Zelinsky Institute of Organic Chemistry RAS, Leninsky Prosp. 47, Moscow, 119991 , Russian Federation, and e Department of Chemistry, M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal. *Correspondence e-mail: bkajaya@yahoo.com The title compound, C22H33N3O4, crystallizes in the triclinic space group P1 with two molecules in a unit cell. The two pyrrole rings are essentially planar (r.m.s. deviation = 0.002 A˚ ) and they form a dihedral angle of 81.24 (10) with each other. The crystal packing is stabilized by C—H interactions and – stacking interactions, forming a three-dimensional network. The Hirshfeld surface analysis and two-dimensional fingerprint plots reveal that the most important contributions for the crystal packing are from H
Keywords :
crystal structure , Hirshfeld surface analysis , π–π stacking inter­actions , C—H⋯π inter­actions , pyrrole ring
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2020
Full Text URL :
Record number :
2622510
Link To Document :
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