Title of article :
Crystal structure of the coordination polymer catena-poly[bis[hydroxy(phenyl)acetato-κ2O1,O2]zinc(II)]-μ2-1,2-bis(pyridin-4-yl)ethane-κ2N:N′]
Author/Authors :
Ming, Shen Fwu Department of Medical Laboratory Science Biotechnology -Yuanpei University, ROC , Fu, Lush Shie Department of Biotechnology - Yuanpei University, ROC
Abstract :
In the title polymeric ZnII compound, [Zn(C8H7O3)2(C12H12N2)]n, the Zn cation is coordinated by two N atoms from 1,2-bis(pyridin-4-yl)ethane unit and four O atoms from two mandelate [or hydroxy(phenyl)acetate] anions in a slightly distorted octahedral coordination geometry. The 1,2-bis(pyridin-4-yl)ethane unit bridges two ZnII cations, related by an inversion centre, to form a polymeric chain along [110]. The crystal structure features extensive O—H⋯O and weak C—H ⋯O hydrogen bonds, with C—H ⋯ π interactions and π–π interactions also being present. The centroid–centroid distance between the phenyl ring of the mandelate group and the 1,2-bis(pyridine-4-yl)ethane moiety is 4.951 (2) Å. The 1,2-bis(pyridin-4-yl)ethane ligand is disordered over two positions, with a refined occupancy of 0.578 (14) for the major component.
Keywords :
crystal structure , disorder , mandelate,1,2-bi(4-pyridyl)ethane , coordination polymer
Journal title :
Acta Crystallographica Section E: Crystallographic Communications