Title of article :
The missing crystal structure in the series of N,N′,N′′-tris­­(pyridinyl)benzene-1,3,5-tricarbox­amides: the 2-pyridinyl derivative
Author/Authors :
Senior, Levi Department of Chemistry - University of Zurich, Switzerland , Linden, Anthony Department of Chemistry - University of Zurich, Switzerland
Pages :
10
From page :
1
To page :
10
Abstract :
In the first reported crystal structure involving the potential ligand N,N′,N′′-tris­(pyridin-2-­yl)benzene-1,3,5-­tricarboxamide, C24H18N6O3, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules via their amide groups into slanted ladder-like chains, in which the uprights of the ladder are formed by the hydrogen-bonding inter­actions and the benzene ring cores of the mol­ecules act as the rungs of the ladder. Only two of the three amide groups in the mol­ecule are involved in hydrogen bonding and this influences the degree of out-of-plane twisting at each amide group, with the twist being more significant for those amide groups participating in hydrogen bonds.
Keywords :
trimesic amide , benzene­tricarboxamide , hydrogen-bonding , crystal structure
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2020
Full Text URL :
Record number :
2623570
Link To Document :
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