Title of article :
Crystal structure and Hirshfeld surface analysis of 4-{2,2-dichloro-1-[(E)-(4-fluorophenyl)diazenyl]ethenyl}-N,N-dimethylaniline
Author/Authors :
Özkaraca, Kadriye Institute of Natural and Applied Science - Erciyes University, Turkey , Akkurt, Mehmet Department of Physics - Faculty of Sciences - Erciyes University, Turkey , Shikhaliyev, Namiq Q. Organic Chemistry Department - Baku State University, Azerbaijan , Askerova, Ulviyya F. Organic Chemistry Department - Baku State University, Azerbaijan , Suleymanova, Gulnar T. Organic Chemistry Department - Baku State University, Azerbaijan , Shikhaliyeva, Irada M. Organic Chemistry Department - Baku State University, Azerbaijan , Bhattarai, Ajaya Department of Chemistry - M.M.A.M.C (Tribhuvan University), Biratnagar, Nepal
Abstract :
In the title compound, C16H14Cl2FN3, the dihedral angle between the two aromatic rings is 64.12 (14)°. The crystal structure is stabilized by a short Cl⋯H contact, C—Cl⋯π and van der Waals interactions. The Hirshfeld surface analysis and two-dimensional fingerprint plots show that H⋯H (33.3%), Cl⋯H/H⋯Cl (22.9%) and C⋯H/H⋯C (15.5%) interactions are the most important contributors towards the crystal packing.
Keywords :
crystal structure , C—Cl⋯π interactions , van der Waals interactions , Hirshfeld surface analysis
