Title of article :
Crystal structure of di­methyl 5-(4-ethyl­phen­yl)-4-[(4-ethyl­phen­yl)ethyn­yl]-6,11-di­phenyl-1,3,6,11-tetra­hydro-2H-6,11-ep­­oxy­cyclo­penta­[a]anthracene-2,2-di­carboxyl­ate
Author/Authors :
Meng, Xiang-Zhen School of Chemistry and Materials Engineering - Chaohu College - Chaohu Anhui, People's Republic of China , Cheng, Dong School of Chemistry and Materials Engineering - Chaohu College - Chaohu Anhui, People's Republic of China
Pages :
13
From page :
1
To page :
13
Abstract :
In the central fused ring system of the title compound, C51H42O5, all of the five-membered rings are in an envelope conformation. The dihedral angle between the two benzene rings in the fused ring system is 74.66 (7)°. In the crystal, mol­ecules are linked by C—H⋯π inter­actions, forming a layer parallel to the ab plane. Each mol­ecule acts as a double donor as well as a double acceptor of the C—H⋯π inter­actions. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (61.4%) and C⋯H/H⋯C (25.3%) contacts.
Keywords :
crystal structure , C—H⋯π inter­actions , Hirshfeld surface analysis , Hirshfeld surface analysis , hexa­dehydro-Diels–Alder reaction
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2020
Full Text URL :
Record number :
2623810
Link To Document :
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