Author/Authors :
Duruskari, Gulnara Sh. Organic Chemistry Department - Baku State University, Z. Azerbaijan , Akkurt, Mehmet Department of Physics - Faculty of Sciences - Erciyes University, Turkey , Mammadova, Gunay Z. Organic Chemistry Department - Baku State University, Z. Azerbaijan , Chyrka, Taras Department of Theoretical and Industrial Heat Engineering (TPT), National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Ukraine , Maharramov, Abel M. Organic Chemistry Department - Baku State University, Z. Azerbaijan
Abstract :
The central thiazolidine ring of the title salt, C16H16N3S+·Br−, adopts an envelope conformation, with the C atom bearing the phenyl ring as the flap atom. In the crystal, the cations and anions are linked by N—H⋯Br hydrogen bonds, forming chains parallel to the b-axis direction. Hirshfeld surface analysis and two-dimensional fingerprint plots indicate that the most important contributions to the crystal packing are from H⋯H (46.4%), C⋯H/H⋯C (18.6%) and H⋯Br/Br⋯H (17.5%) interactions.
Keywords :
charge assisted hydrogen bonding , thiazolidine ring , envelope conformation , Hirshfeld surface analysis
