Title of article :
(E)-3-{[(2-Bromo-3-methylphenyl)imino]methyl}benzene-1,2-diol: crystal structure and Hirshfeld surface analysis
Author/Authors :
Doğan, Onur Erman Ondokuz Mayıs University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , Dege, Necmi Ondokuz Mayıs University - Faculty of Arts and Sciences - Department of Physics, Turkey , Ağar, Erbil Ondokuz Mayıs University - Faculty of Arts and Sciences - Department of Chemistry, Turkey , Fritsky, Igor O. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine
Abstract :
The title compound, C14H12BrNO2, was synthesized by the condensation
reaction of 2,3-dihydroxybenzaldehyde and 2-bromo-3-methylaniline. It crystallizes in the centrosymmetric triclinic space group P1. The configuration about
the C N bond is E. The dihedral angle between the planes of the 5-(2-bromo-3-
methylphenyl ring and the catechol ring is 2.80 (17). In the crystal, O—HO
hydrogen-bond interactions consolidate the crystal packing.
Keywords :
crystal structure , Schiff base , hydrogen bonds , Hirshfeld surface analysis , O⋯O interaction
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
