Title of article :
The structure and Hirshfeld surface analysis of the salt 3-methacryl­amido-N,N,N-tri­methyl­propan-1-aminium 2-acryl­amido-2-methyl­propane-1-sulfonate
Author/Authors :
Wickramasinhage, Ravindra N. Department of Chemistry - University of Otago, New Zealand , McAdam, C. John Department of Chemistry - University of Otago, New Zealand , Hanton, Lyall R. Department of Chemistry - University of Otago, New Zealand , Moratti, Stephen C. Department of Chemistry - University of Otago, New Zealand , Simpson, Jim Department of Chemistry - University of Otago, New Zealand
Pages :
17
From page :
1
To page :
17
Abstract :
The title salt, C10H21N2O+·C7H12NO4S−, comprises a 3-methacryl­amido-N,N,N-tri­methyl­propan-1-aminium cation and a 2-acryl­amido-2-methyl­propane-1-sulfonate anion. The salt crystallizes with two unique cation–anion pairs in the asymmetric unit of the ortho­rhom­bic unit cell. The crystal studied was an inversion twin with a 0.52 (4):0.48 (4) domain ratio. In the crystal, the cations and anions stack along the b-axis direction and are linked by an extensive series of N—H⋯O and C—H⋯O hydrogen bonds, forming a three-dimensional network. Hirshfeld surface analysis was carried out on both the asymmetric unit and the two individual salts. The contribution of inter­atomic contacts to the surfaces of the individual cations and anions are also compared.
Keywords :
crystal structure , 3- Hirshfeld surface analysis , methacryl­amido-N,N,N-tri­methyl­propan-1-aminium , 2-acryl­amido-2-methyl­propane-1-sulfonate , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2625271
Link To Document :
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