Title of article :
The crystal structure of ((cyclo­hexyl­amino){(Z)-2-[(E)-5-meth­­oxy-3-nitro-2-oxido­benzyl­­idene-κO]hydrazin-1-yl­­idene-κN2}methane­thiol­ato-κS)(di­methyl sulfoxide-κS)platinum(II): a supra­molecular two-dimensional network
Author/Authors :
Arafath, Md. Azharul Department of Chemistry - Shahjalal University of Science and Technology, Bangladesh , Kwong, Huey Chong School of Chemical Sciences - Universiti Sains Malaysia, Malaysia , Adam, Farook School of Chemical Sciences - Universiti Sains Malaysia, Malaysia
Pages :
10
From page :
1
To page :
10
Abstract :
The PtII atom in the title complex, [Pt(C15H18N4O4S)(C2H6OS)], exists within a square-planar NS2O donor set provided by the N, S, O atoms of the di-anionic tridentate thio­semicarbazo ligand and a dimethyl sulfoxide S atom. The two chelate rings are coplanar, subtending a dihedral angle of 1.51 (7)°. The maximum deviation from an ideal square-planar geometry is seen in the five-membered chelate ring with an S—Pt—S bite angle of 96.45 (2)°. In the crystal, mol­ecules are linked via N—H⋯O, C—H⋯O, C—H⋯N and C—H⋯π inter­actions into two-dimensional networks lying parallel to the ab plane. The conformations of related cyclo­hexyl­hydrazine-1-carbo­thio­amide ligands are compared to that of the title compound.
Keywords :
C—H⋯π inter­actions , crystal structure , cyclo­hexyl­hydrazinecarbo­thio­amide , soft Lewis base , carbo­thio­amide Schiff base , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2625278
Link To Document :
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