Author/Authors :
Kuzevanova, Iryna S. Department of General and Inorganic Chemistry - National Technical University of Ukraine "Igor Sikorsky Kyiv Polytechnic Institute", Ukraine , Naumova, Dina D. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine , Terebilenko, Kateryna V. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine , Shova, Sergiu Department of Inorganic Polymers - "Petru Poni" Institute of Macromolecular Chemistry, Romanian Academy of Science, Romania , Gural'skiy, Il'ya A. Department of Chemistry - Taras Shevchenko National University of Kyiv, Ukraine
Abstract :
In the title polymeric complex, {[FePt(CN)4(H2O)2]·2C3H6O}n, the FeII cation has an octahedral [FeN4O2] geometry being coordinated by two water molecules and four cyanide anions. The Pt cation is located on an inversion centre and has a square-planar coordination environment formed by four cyanide groups. The tetracyanoplatinate anions bridge the FeII cations to form infinite two-dimensional layers that propagate in the bc plane. Two guest molecules of acetone per FeII are located between the layers. These guest acetone molecules interact with the coordinated water molecules by O—H⋯O hydrogen bonds.
Keywords :
crystal structure , Hofmann clathrate , iron(II) , Similar articlesReuse permissionsPowerPoint slides
