Author/Authors :
Riemersma, Charl F. Organic Chemistry and Catalysis - Debye Institute for Nanomaterials Science - Faculty of Science - Utrecht University, The Netherlands , Monkcom, Emily C. Organic Chemistry and Catalysis - Debye Institute for Nanomaterials Science - Faculty of Science - Utrecht University, The Netherlands , Klein Gebbink, Robertus J. M. Organic Chemistry and Catalysis - Debye Institute for Nanomaterials Science - Faculty of Science - Utrecht University, The Netherlands , Lutz, Martin Bijvoet Center for Biomolecular Research - Crystal and Structural Chemistry - Faculty of Science, Utrecht University, The Netherlands
Abstract :
The title compound, [Fe(CF3SO3)2(C4H8O)4], is octahedral with two trifluoromethanesulfonate ligands in trans positions and four tetrahydrofurane molecules in the equatorial plane. By the conformation of the ligands the complex is chiral in the crystal packing. The compound crystallizes in the Sohncke space group P212121 and is enantiomerically pure. The packing of the molecules is determined by weak C—H⋯O hydrogen bonds. The crystal studied was refined as a two-component inversion twin.
