Title of article :
Synthesis and crystal structure of tert-butyl 1-(2-iodo­benzo­yl)cyclo­pent-3-ene-1-carboxyl­ate
Author/Authors :
Yin, Dejing School of Biotechnology - Jiangnan University, People's Republic of China
Pages :
8
From page :
1
To page :
8
Abstract :
1-(2-Iodo­benzo­yl)-cyclo­pent-3-ene-1-carboxyl­ates are novel substrates to construct bi­cyclo­[3.2.1]octa­nes with anti­bacterial and anti­thrombotic activities. In this context, tert-butyl 1-(2-iodo­benzo­yl)-cyclo­pent-3-ene-1-carboxyl­ate, C17H19IO3, was synthesized and structurally characterized. The 2-iodo­benzoyl group is attached to the tertiary C atom of the cyclo­pent-3-ene ring. The dihedral angle between the benzene ring and the mean plane of the envelope-type cyclo­pent-3-ene ring is 26.0 (3)°. In the crystal, pairs of C-H⋯O hydrogen bonds link the mol­ecules to form inversion dimers.
Keywords :
crystal structure , substrate , cyclo­pentene ring , hydrogen bonding
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2625362
Link To Document :
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