Title of article :
Crystal structure, DFT and MEP study of (E)-2-[(2-hy­dr­oxy-5-meth­­oxy­benzyl­­idene)amino]­benzo­nitrile
Author/Authors :
Haque Faizi, Md. Serajul PG Department of Chemistry - Langat Singh College, India , Dege, Necmi Ondokuz Mayıs Universit- Faculty of Arts and Sciences - Department of Physics, Turkey , Çiçek, Ceren Ondokuz Mayıs University - Faculty of Arts and Sciences -- Department of Chemistr ,Turkey , Agar, Erbil Ondokuz Mayıs University - Faculty of Arts and Sciences -- Department of Chemistr ,Turkey , Fritsky, Igor O. National Taras Shevchenko University - Department of Chemistry, Ukraine
Pages :
11
From page :
1
To page :
11
Abstract :
The asymmetric unit of the title compound, C15H12N2O2, contains two crystallographically independent mol­ecules in which the dihedral angles between the benzene rings in each are 13.26 (5) and 7.87 (5)°. An intra­molecular O—H⋯N hydrogen bonds results in the formation of an S(6) ring motif. In the crystal, mol­ecules are linked by weak C—H⋯O and C—H⋯N hydrogen bonds, forming layers parallel to (011). In addition, π–π stacking inter­actions with centroid–centroid distances in the range 3.693 (2)–3.931 (2) Å complete the three-dimensional network.
Keywords :
crystal structure , 2-hy­droxy-5-meth­oxy­benzaldehyde , weak hydrogen bonding , 2-amino­benzo­nitrile
Journal title :
Acta Crystallographica Section E: Crystallographic Communications
Serial Year :
2019
Full Text URL :
Record number :
2627913
Link To Document :
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