Author/Authors :
Tylianakis, Emmanuel University of Crete - Materials Science and Technology Department, Greece , Klontzas, Emmanouel University of Crete - Department of Chemistry, Greece , Froudakis, George E University of Crete - Department of Chemistry, Greece
Abstract :
Open-framework materials have been proposed as potential materials for hydrogen storage. Metal–organic framework (MOF) and covalent–organic framework (COF) materials are under extensive study to discover their storage abilities. In particular the IRMOF family of materials have been considered as ideal to study the effect of different factors that affect the hydrogen storage capacity. In this paper, we analyse the effect of different factors such as surface area, pore volume and the interaction of hydrogen with the molecular framework on the hydrogen uptake of such materials. Through this analysis we propose guidelines to enhance hydrogen storage capacity of already synthesized materials and recommend advanced materials for this application