Author/Authors :
Il’ina, I. V. Russian Academy of Sciences, Siberian Branch - Vorozhtsov Novosibirsk Institute of Organic Chemistry, Russia , Kurbakova, S. Yu. Russian Academy of Sciences, Siberian Branch - Vorozhtsov Novosibirsk Institute of Organic Chemistry, Russia , Volcho, K. P. Russian Academy of Sciences, Siberian Branch - Vorozhtsov Novosibirsk Institute of Organic Chemistry, Russia , Salakhutdinov, N. F. Russian Academy of Sciences, Siberian Branch - Vorozhtsov Novosibirsk Institute of Organic Chemistry, Russia , Anikeev, V. I. Russian Academy of Sciences, Siberian Branch - Boreskov Institute of Catalysis, Russia
Abstract :
The use of a system consisting of flow-type reactor, supercritical fluid containing isopropanol/ CO2 and alumina as a catalyst allows the one-pot isomerization of α- and β-pinene epoxides into campholenic aldehyde and myrtanal and Meerwein–Ponndorf–Verley reduction of these aldehydes to the corresponding alcohols.
Keywords :
Meerwein–Ponndorf–Verley reduction , Supercritical isopropanol , Supercritical CO2 , Alumina , Pinene epoxide , Campholenic alcohol , Myrtanol
