Title of article :
SYNTHESIS, CHARACTERIZATION AND ANTIMICROBIAL ACTIVITY OF SOME METAL IONSWITH 2-THIOACETIC-5-PHENYL-1,3,4- OXADIAZOLE
Author/Authors :
Ibraheem, Hanan Al-Nahrain University - College of Science - Department of Chemistry, Iraq , Adel, Hadeel Al-Nahrain University - College of Science - Department of Chemistry, Iraq , Ahmed, Ahmed Al- Mustansiryah University - College of Science - Polymer Research unit, Iraq , Salih, Nadia Al-Nahrain University - College of Science - Department of Chemistry, Iraq , Salimon, Jumat National University of Malaysia - School of Chemical Science Food Technology, Malaysia , Graisa, Abdualbasit National University of Malaysia - School of Chemical Science Food Technology, Malaysia , Farina, Yang National University of Malaysia - School of Chemical Science Food Technology, Malaysia , Yousif, Emad Al-Nahrain University - College of Science - Department of Chemistry, Iraq
Abstract :
New metal complexes of the ligand 2-thioacetic-5-phenyl-1,3,4-oxadiazole with the metal ions Ni(II), Cu(II), Zn(II), Cd(II) and Sn(II) were prepared in alcoholic medium. The prepared complexes were characterized by FTIR Spectroscopy, electronic spectroscopy, mass spectroscopy 1HNMR, 13CNMR, magnetic susceptibility and conductivity measurements. From the spectral measurements, monomer structures for the complexes were proposed. Square planar geometry was proposed for the copper complex. The other complexes were proposed to be tetrahedral. Preliminary in vitro tests for antimicrobial activity show that all prepared compounds display good activity to Staphylococcus aureus, Escherishia coli, Pseudononas aeroginosa and Cndida albicans.
Keywords :
carboxylate , 1 , 3 , 4 , oxadiazole , metal complexes , antimicrobial activity.
Journal title :
Al-Nahrain Journal Of Science
Journal title :
Al-Nahrain Journal Of Science
