Author/Authors :
NAEEM, ABDUL University of Peshawar - National Centre of Excellence in Physical Chemistry, Pakistan , ALI, HAMID University of Peshawar - National Centre of Excellence in Physical Chemistry, Pakistan , MUSTAFA, SYED University of Peshawar - National Centre of Excellence in Physical Chemistry, Pakistan , QAMAR, SULTANA University of Peshawar - National Centre of Excellence in Physical Chemistry, Pakistan , TASLEEM, SYED Kohat University of Science and Technology - Department of Chemistry, Pakistan , BEGUM, DILARA University of Peshawar - National Centre of Excellence in Physical Chemistry, Pakistan
Abstract :
A comprehensive kinetic study of the xanthate ions sorption on CuS was performed as a function of different experimental conditions of temperature and concentration. Adsorption kinetics experiments indicated that xanthate adsorption onto the CuS reached steady-state within approximately seven and ten minutes from the start of the experiment in case of high and lower concentration of xanthate anions respectively. Legregran s first order equation was applied for the determination of the rate constant. Temperature had a positive effect on kinetics of the process and from the temperature dependence of the rate constant, energy of activation was calculated.