Title of article :
CHARGE TRANSFER COMPLEXES BETWEEN SOME CRYPTANS WITH TETRACYANOETHYLENE AND 2-HYDROXY-1,4-NAPTHOQUINONE
Author/Authors :
Hussain, Sabri Mohammed. University of Anbar - College of medicine, Iraq , Jamal, Khalid University of Anbar - College of medicine, Iraq
Abstract :
The intermolecular charge transfer ( CT ) complex of two cryptands , viz , K221 and K222 (as donors and tow acceptors, viz , tetracyanoethylene (TCNE) and 2-hydroxy-1,4-napthoquinon were studied ion Uv-visible region in dichloromethane (DCM)as solvent at 298.2k .It was found that the basicity of cryptand played an important role in the formation constant Kc value obtained . The nature of CT complexes formed were achieved by calculation of oscillator strength
Keywords :
Charge Transfer , Cryptands , Tetracyanoethylene , 2 , hydroxy , 1 , 4 , napthoquinone
Journal title :
Journal Of University Of Anbar For Pure Science
Journal title :
Journal Of University Of Anbar For Pure Science