Author/Authors :
Alazawi, Shayma A.S. University of Baghdad - College of Science for Women - Chemistry Department, Iraq
Abstract :
This paper presents the preparation and study of some mixed ligand complexes of caffeine, y-picoline and thiocyanete ions with some metal ions. The reaction was carried out in (1:1) ethanol: water mixture using the appropriate molar ratio of metal: ligand (1:1:1:2) as required. The resulting products were found to be solid crystalline complexes which have been characterized by using I.R, U.V-Visible spectra, elemental analysis, thermal stability, molar conductivity and magnetic properties. The general formula of the prepared complexes given [M(CA)( y-pico)X2] was suggested as. Where M2+ = V02+, Co2+, Ni2+, Cu2+, Zn2+, Cd2+