Title of article :
Preparation and Characterization of Some Metal Complexes with Heterocyclic Azo Ligand (4-SuBAI)
Author/Authors :
habiban, abdullah m. a. university of kufa - college of education for women - department of chemistry, iraq , mahmoud, waleed a. university of baghdad - college of science for women - department of chemistry, Iraq , kareem, tamara a. university of baghdad - college of science for women - department of chemistry, Iraq , kareem, tamara a. ministry of science - chemistry research center - department of materials science, Iraq
Abstract :
The preparation and characterization of the Cu (II), Co(II), Ni(II), Zn(II), Cd(II), and Hg(II) metal complexes of heterocyclic azo ligand 2-[(4`-sulphamide phenyl) azo] -4,5-diphenyl imidazole (4-SuBAI) have been studied by elemental analysis, FT-IR and UV-Vis Spectroscopic, magnetic moment and molar conductance methods. The analytical data showed that all chelate complexes were prepared with (metal-ligand) ratio of (1:2).The general formula of these complexes was [ML2X2]. nH2O [were L=2-[(4`-sulphamide phenyl) azo]-4,5-diphenyl imidazole and X=Cl, and the octahedral geometry were suggested for these complexes.
Keywords :
Characterization , Metal Complexes , Heterocyclic , Azo , Ligand
Journal title :
Baghdad Science Journal
Journal title :
Baghdad Science Journal
