• Title of article

    Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid

  • Author/Authors

    neema, ban z. university of baghdad - collage of education for pure sciences, ibn-al-hatham - department of chemistry, Iraq , sarhan, basima m. university of baghdad - collage of education for pure sciences, ibn-al-hatham - department of chemistry, Iraq

  • From page
    588
  • To page
    596
  • Abstract
    3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid (HNP) a new ligand was synthesized by reaction of Tyrosine with (4-Nitrobenzoyl isothiocyanate) by using acetone as a solvent. The prepared ligand (HNP) has been characterized by elemental analysis (CHNS), infrared (FT-IR), electronic spectral (Ultraviolet visible) and(1H,13C-Nuclear Magnetic Resonance) spectra. Some Divalent metal ion complexes of (HNP) were prepared and spectroscopic studies by Fourier transform infrared (FTIR), electronic spectral(UV-Vis), molar conductance, magnetic susceptibility and atomic absorption. The results measured showed the formula of six prepared complexes were [M (HNP)2] (M+2 = Manganese, Cobalt, Nickel, Znic, Cadmium and Mercury),from the obtained data tetrahedral structure suggested for all complexes, except Copper complex has a square planer geometry.
  • Keywords
    Tyrosine , Divalent Metal Ion , 4 , Nitrobenzoyl isothiocyanate.
  • Journal title
    Baghdad Science Journal
  • Journal title
    Baghdad Science Journal
  • Record number

    2691915