Title of article :
Study on Electrochemical Behavior of Hydrazine at a Glassy Copper Nanoparticles
Author/Authors :
Karim-Nezhad, Ghasem Department of Chemistry - Payame Noor University, Tehran , Pashazadeh, Sara Electroanalytical Chemistry Laboratory - Department of Chemistry - Faculty of Sciences - Azarbaijan Shahid Madani University, Tabriz , Honarmand, Samira Department of Chemistry - Payame Noor University, Tehran
Abstract :
In this study, a novel and convenient electrochemical sensor was fabricated by using dripping well-dispersed
graphene oxide nanosheets, electropolymerization of poly glycine (p-Gly) and in situ plating of metallic copper
na was further employed to investigate the electrochemical
behavior of hydrazine. Scanning electron microscopy and energy dispersive X-ray spectrometry were used for the
electrode shifts by about 150 mV toward negative values compared with that on the bare electrode. The kinetic
) and charge transfer rate constant (k) for the oxidation of
D) of hydrazine was also
estimated using chronoamperometry. The dynamic detection range of this sensor to hydrazine was 5- 60 and 80-
quantitation are
5.33 μM and 17.77 μM, respectively. A new voltammetric method for determination of hydrazine was erected and
shows good sensitivity and selectivity, wider linear relationship, very easy surface update and good stability.
Keywords :
Hydrazine , Copper Nanoparticle , Glycine , Graphene Oxide Nanosheets , Modified Glassy Carbon Electrode
Journal title :
Iranian Journal of Analytical Chemistry