• Title of article

    A Novel Rearrangement of Chromium Allyloxy(aryl)carbene Complexes Catalyzed by TPd(0)

  • Author/Authors

    Sakurai، Hidehiro نويسنده , , Narasaka، Koichi نويسنده , , Tanabe، Katsuhiko نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 1999
  • Pages
    -74
  • From page
    75
  • To page
    0
  • Abstract
    Chromium allyloxy(aryl)carbene complexes undergo formal [2,3]- or [l,2]-sigmatropic rearrangement by the catalytic use of Pd(PPh3)4 under CO atmosphere. The reaction is considered to proceed via palladium aroyl pi-allyl complex, which is converted to the corresponding aryl ketones by reductive elimination.
  • Keywords
    electrochemical impedance spectroscopy , Aluminium , anodic films
  • Journal title
    CHEMISTRY LETTERS
  • Serial Year
    1999
  • Journal title
    CHEMISTRY LETTERS
  • Record number

    27129