Title of article :
Introduction of a Benzoquinone Pharmacophore on a Labdane Platform
Author/Authors :
Aslaoui, Jamila Université Joseph Fourier, France , Morin, Christophe Université Joseph Fourier, France
Abstract :
The allylic alcohol of the side-chain of larixol was converted into an exo 1,3-diene through trifluoroacetylation followed by palladium-catalyzed elimination; this allowed the introduction of abenzoquinone pharmacophore on this labdane platform in ‘one-pot’ from allylic trifluoroacetates.
Keywords :
1 , 3 , diene , allylic trifluoroacetate , larixol , quinone , labdane
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
