Title of article :
The Reaction of Alkenes with AgNO2/TMSCl: The Synthesis of 1,2,5-Oxadiazole-2-Oxides (Furoxans) Via Nitroso Nitrates
Author/Authors :
Demir, Ayhan S. Middle East Technical University - Department of Chemistry, Turkey , Findik, Hamide Middle East Technical University - Department of Chemistry, Turkey
Abstract :
The reaction of AgNO2/TMSCl with olefins affords nitrosonitrate, which are converted into a-nitroximes in good yield. Both nitrosonitrate and nitroximes are converted with acids into furoxane in highyield. The reaction of AgNO2 with TMSCl furnished first N2O3 and hexamethylsiloxane. The nitroso nitrates are obtained by addition of N2O3 to the olefines.
Keywords :
Nitrosonitrate , nitroximes , furoxane , a , nitroximes
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
