Title of article :
A New and Convenient Method of Generating Alkyl Cyanides from Alcohols and Thiols Using 2,4,6-Trichloro[1,3,5]Triazine/n-Bu4NCN
Author/Authors :
Akhlaghinia, Batool damghan university - Department of Chemistry, دامغان, ايران , Roohi, Elham damghan university - Department of Chemistry, دامغان, ايران
Abstract :
Alkyl cyanides are prepared in good to excellent yields (average yield 93% )by treatment of alcohols and thiols with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NCN in refluxing acetonitrile. This method is highly selective for conversion of 1° alcohols in the presence of 2° and 3° ones and thiols.
Keywords :
2 , 4 , 6 , Trichloro[1 , 3 , 5] triazine(TT) , alcohol , thiol , alkyl cyanide
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
