Title of article :
Novel and Highly Selective Conversion of Alcohols, Thiols and Trimethylsilyl Ethers to Alkyl Nitrites with 2,4,6-Trichloro[1,3,5]triazine/n-Bu4NNO2 System
Author/Authors :
Akhlaghinia, Batool damghan university - Department of Chemistry, دامغان, ايران , Roohi, Elham damghan university - Department of Chemistry, دامغان, ايران
Abstract :
Alkyl nitrites were prepared in good to excellent yields by treatment of alcohols, thiols and trimethylsilyl ethers with 2,4,6-trichloro[1,3,5]triazine/n-Bu4NNO2 in refluxing acetonitrile. This method is highly selective for the conversion of primary alcohols to alkyl nitrites in the presence of secondary and tertiary alcohols, thiols and trime thylsilyl ethers.
Keywords :
2 , 4 , 6 , Trichloro[1 , 3 , 5] triazine(TT) , alcohol , thiol , trimethylsilyl ether , alkyl nitrite
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
