Title of article :
Indium-Mediated Allylation of α ,α -Dichloroketones: The Synthesis of 1,1-Dichloro-2-organyl-pent-4-en-2-ols
Author/Authors :
Peppe, Clovis Universidade Federal de Santa Maria - Departamento de Química, Brazil , Nóbrega, José A. Universidade Estadual da Paraíba - Departamento de Química, Brazil , Drehmer, Lia D. Universidade Federal de Santa Maria - Departamento de Química, Brazil , Martins, Marcos A.P. Universidade Federal de Santa Maria - Departamento de Química, Brazil
Abstract :
The allylindium reagents obtained from metallic indium and allyl bromides, in THF, couple chemioselectively to the carbonyl group of a,a- dichloroketones to afford 1,1-dichloro-2-organyl-pent-4-en-2-ols in good to excellent yields
Keywords :
Indium , allylindium , allylation , dichloroketones
Journal title :
letters in organic chemistry
Journal title :
letters in organic chemistry
