Author/Authors :
Ashirov, Ruslan V Kazan State Medical University, Butlerov St., 49, Kazan 420012, Russia , Balandina, Alsu A Institute of Organic and Physical Chemistry at the Kazan Scientific Centre - Russian Academy of Sciences, Arbuzov St., 8, Kazan 420088, Russia , Kharlamov, Sergey V. Institute of Organic and Physical Chemistry at the Kazan Scientific Centre - Russian Academy of Sciences, Arbuzov St., 8, Kazan 420088, Russia , Appolonova, Svetlana A FSUE Antidope Centre, Elizavetinskiy Av., 10, Moscow 105005, Russia , Figadere, Bruno Laboratoire de Pharmacognosie associé au CNRS (BioCIS) - Université Paris-Sud, Faculté de Pharmacie, rue JB. Clément, Châtenay-Malabry, France , Latypov, Shamil K Institute of Organic and Physical Chemistry at the Kazan Scientific Centre - Russian Academy of Sciences, Arbuzov St., 8, Kazan 420088, Russia , Plemenkov, Vitali V Kazan State Medical University, Butlerov St., 49, Kazan 420012, Russia
Abstract :
: Sesquiterpene adducts have been obtained by the reactions of 3-methyl-3-cyanocyclopropene with
(-) -pinene and (-)carvone, proceeding by Alder-ene pathway. In the reaction with -pinene only one
diastereoisomer (~95 %) was formed, while in the case of carvone a mixture of two diastereoisomers almost in
equal quantities (55:45) was obtained.
