Title of article :
Ligand Adducts of Bis(acetylacetonato) Copper(II), Bis(3-chloroacetylacetonato) Copper(II) with 4,4’-bipyridine, and Propylene Spacered Bis-viologen
Author/Authors :
Gatea ، Azhar H. Department of Chemistry - College of Science - University of Thi-Qar , Abdul-Hassan ، W.S. Department of Chemistry - College of Science - University of Thi-Qar , Ali ، S.A. Department of Chemistry - College of Science - University of Thi-Qar , Mahdi ، Z.M. Department of Pharmacy - Mazaya University College
Abstract :
Bis(acetylacetonato) copper (II): CuA, bis(3-chloroacetylacetonato) copper: CuA-Cl, and their adducts with 4,4`-bipyridine are synthesized. These copper (II) complexes are characterized by mass, FT-IR, UV-Visible, and XRD spectrometries. The interaction of copper (II) complexes: CuA and CuA-Cl with 4,4`-bipyridine, Bpy, and bis-viologen, V22+.2PF6- are studied in solution by electronic absorption spectroscopy. The solutions of adducts happened between CuA and CuA-Cl with V22+.2PF6-are reduced by activated Zn powder to afford viologen-based switches within adducts structures.
Keywords :
acetylacetone , Adduct , 4 , 4`-Bipyridine , Viologen , π -Dimer , Copper (II) complexes
Journal title :
Journal of Medicinal and Chemical Sciences
Journal title :
Journal of Medicinal and Chemical Sciences
