Author/Authors :
akinsola, si university of ilorin - department of physics, Ilorin, Nigeria , akinsola, si crown-hill university - department of physical and mathematical sciences, Ilorin, Nigeria , adedayo, ks university of maiduguri - department of physics, Maiduguri, Nigeria , alabi, ab university of ilorin - department of physics, Ilorin, Nigeria , olanrewaju, db landmark university - department of physical sciences, Omu-Aran, Nigeria , ajayi, aa afe babalola university - department of mathematical and physical sciences, Ado-Ekiti, Nigeria , babalola, oa sheda science and technology complex, Abuja, Nigeria
Abstract :
Nanostructured SnO_2 thin films were grown by the chemical spray pyrolysis (CSP) method. Homemade spray pyrolysis technique is employed to prepare thin films. SnO_2 is wide band gap semiconductor material whose film is deposited on glass substrate. A gold nanoparticle-doped tin oxide thin film (AuTO) was also prepared. UV-VIS (ultraviolet visible) spectroscopy and four-point probe analysis are done for optical and electrical analysis. UV-Visible absorption spectra show that the band gap of SnO_2 thin film is 3.78 eV and 3.82 eV for AuTO. Band gap of SnO_2 thin film can be tuned that it can be used in optical devices. The films have transmittance increases (to about 60%) and the absorbance decreases in the visible region of the electromagnetic spectrum. The electrical conductivity of the Tin Oxide is enhanced by functionalizing with the Gold nanoparticles. It is higher than that of the Tin oxide only; 0.77 x 10^-2 (Ohm cm)^-1 and 3.55 x 10^-2 (Ohm cm)^-1 for SnO_2 and AuTO respectively. These properties reveal that Tin Oxide doped with gold can actually be a good material for a transparent conducting oxide to be used in photovoltaic fabrication and in electronics.
Keywords :
Tin oxide , Spray pyrolysis , gold , nanoparticle , Transparent conducting oxide (TCO)