Author/Authors :
krisnandi, yuni krisyuningsih universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia , priantini, tania universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia , faisal, muhammad universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia , yunarti, rika tri universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia , saragi, indah revita universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia , gunlazuardi, jarnuzi universitas indonesia - faculty of mathematics and natural science - department of chemistry, Depok, Indonesia
Abstract :
Grass-like structured mesoporous carbon was prepared by the soft-template method using triblock copolymer Pluronic F127, affording an organic–organic composite structure between phloroglucinol and formaldehyde. Thermogravimetric analysis revealed that the as-synthesized mesoporous carbon is stable to 900 °C, and X-Ray Diffraction (XRD) analysis confirmed the presence of carbon material structures at 2θ values of 22.020° and 42.420°. A hysteresis loop at relative partial pressures (P/Po) between 0.45 and 0.85 was observed in the N2 adsorption isotherm, indicating that the solid material exhibits mesoporous characteristics, with a homogeneous pore size distribution of 8.863 nm. Scanning Electron Microscope (SEM) images revealed that the bulk carbon surface exhibits a uniform grass-like structure. Furthermore, the as-synthesized mesoporous carbon was investigated for the adsorption of a diazo dye Acid Red 119, and it exhibited an adsorption capacity of 217.7389 mg/g; this capacity is 1.53 times greater than that of commercial activated carbon. Therefore, this mesoporous carbon is a potential adsorbent for the treatment of synthetic coloring waste.
Keywords :
mesoporous carbon , soft , template method , adsorbent , adsorption , grass , like structure , diazo dye Acid Red 119