Title of article
Baeyer–Villiger Oxidations in Ionic Liquids. A Facile Conversion of Ketones to Esters and Lactones
Author/Authors
Yadav، J. S. نويسنده , , Reddy، B. V. S. نويسنده , , Basak، A. K. نويسنده , , Narsaiah، A. V. نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
-247
From page
248
To page
0
Abstract
A variety of cyclic and acyclic ketones underwent readily oxidation with m-chloroperbenzoic acid (m-CPBA) in ionic liquid 1butyl-3-methylimidazolium tetrafluoroborate [bmim]BF4 to afford esters/lactones with high selectivity, ease of product separation and in excellent chemical yields. The reaction proceeded smoothly in ionic liquid without the need of any additional acid or base catalyst. The ketones show enhanced reactivity in ionic liquids thereby reducing reaction times and improving the yields significantly.
Keywords
prediction , Surface finish , grinding , Application-production research , Genetic-fuzzy system , Power requirement
Journal title
CHEMISTRY LETTERS
Serial Year
2004
Journal title
CHEMISTRY LETTERS
Record number
27600
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