Title of article
Photo-Assisted Hydrogen Transfer from Alcohol to Limonene Catalyzed by [Rh6(CO)16]
Author/Authors
Yanagawa، Akihisa نويسنده , , Hatae، Tomomi نويسنده , , Yada، Satoru نويسنده , , Sugimori، Akira نويسنده , , Takagi، Yuzuru نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-898
From page
899
To page
0
Abstract
Partial hydrogenation of the exo-olefinic bond in limonene to carvomenthene proceeds smoothly by photocatalytic hydrogen transfer from 2-propanol using [Rh6(CO)16] as a catalyst under UV-irradiation in the presence of acetone. Hydrogen gas evolves after the formation of carvomenthene has been completed. 1-Hydroxy-1-methylethyl radical formed in the reaction of photochemically excited acetone with 2-propanol serves both as an activator for the catalyst and as a hydrogen source.
Keywords
Restricted latent class models , Identifiability , Parametric bootstrap , Model diagnosis , Goodness of fit
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
27668
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