Title of article
Control Factors of Two Reaction Modes of Pentacoordinate 1,2-Oxasiletanides, the Peterson Reaction and HomoBrook Rearrangement
Author/Authors
Okazaki، Renji نويسنده , , Naganuma، Kenji نويسنده , , Kawashima، Takayuki نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-1138
From page
1139
To page
0
Abstract
Thermolyses of pentacoordinate 1,2-oxasiletanides with or without a neopentyl group at the 3-position in the presence of a proton source afforded the corresponding olefin and/or alcohol, indicating that they are the intermediates of both the Peterson reaction and homo-Brook rearrangement which are two possible modes in the reaction of (beta)-hydroxyalkylsilanes with bases.
Keywords
Parametric bootstrap , Restricted latent class models , Goodness of fit , Identifiability , Model diagnosis
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
27884
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