Title of article
Synthesis, Structure and Catalytic Activity of a Seven-Coordinate Titanium(IV) Tris(pyridine2-thiolate) Complex
Author/Authors
Yuushou، Nakayama, نويسنده , , Kaoru، Miyamoto, نويسنده , , Akira، Nakamura, نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-390
From page
391
To page
0
Abstract
Reaction of TiCl4 with three equivalents of Me3SiSPy (SPy = pyridine-2-thiolate) cleanly gave a tris(thiolate) complex, TiCl(SPy)3. THF (1). The pentagonal bipyramidal geometry of 1 was revealed by X-ray crystallography. This complex showed catalytic activity for the polymerization of ethylene and styrene upon activation with methylaluminoxane.
Keywords
Bibliometrics , productivity rankings , refereed journals , research in probability and statistics
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
27903
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