Title of article
Rapid, Highly Linear-Selective Dehydrocoupling of Phenylsilane with New Group 4 Metallocene-Based Combination Catalysts
Author/Authors
Woo، Hee-Gweon نويسنده , , Song، Sun-Jung نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1999
Pages
-456
From page
457
To page
0
Abstract
The dehydrocoupling of phenylsilane with Cpʹ2MCl2/Red-Al (Cpʹ = C5H5 or C51Me5; M = Ti, Zr, Hf; Red-Al = Na[H2AI(OCH2CH2OMe)2]) combination catalysts rapidly produces linear polyphenylsilanes, and the linear selectivity drastically decreases in the order of Cp(C5Me5)Hf > Cp2Hf > Cp(C5Me5)Zr > Cp2Zr > Cp2Ti; in the presence of solvent (neat > toluene > THF) and 4 A molecular sieve; with heating.
Keywords
productivity rankings , refereed journals , research in probability and statistics , Bibliometrics
Journal title
CHEMISTRY LETTERS
Serial Year
1999
Journal title
CHEMISTRY LETTERS
Record number
28031
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